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I just downloaded the software yesterday and am trying to figure out how to assemble parts. Is this feature available in the education version?
Yep, this is available in all versions of Creo. For more info on assemblies and constraints, I would recommend checking out our curriculum "How to Model Almost Anything", which you can download here: http://www.ptc.com/academic-program/k-12-program/students/first/training
Let me know how it goes.