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how the Windchill BOM will work, If we choose different part numbers.
What will be compared in the result ?
You might need to restate your question clearer. Are you referring to changing component on a BOM then comparing? It will show that in one iteration a part exists and then in the next, its gone. Reverse is true for added components. Nothing then something. There are options to include part differences.
I agree with what @avillanueva said.
I would add that if you use the "replace" command in the WTPart structure, the compare will show that the first part number was changed for the second one.
Can you clarify your question @AP_9587236?