It's the way you've (implicitly) parenthesized the expression. While what you wanted was (-4)°C, what you actually have is -(4°C). BTW, your stated expectation for T3 is wrong. The difference between two Celcius temperatures is not a Celsius temperature. While common usage uses °C for both temperatures and temperature differences, the two are actually quite distinct units and require different conversions. In Mathcad °C is used only for temperatures, not temperature differences.