Two problems:
1) You should turn on the option "Units/Constants in Symbolics" and then recalculate the worksheet (Ctrl+F5)

The symbolics still doesn't not know anything about units now but this option at least avoid that units get labeled wrongly as "Variable". I have no idea why this option is not permanently on per default.
2) If you want to see a value as percent, you can't simply type a "%" in the unit placeholder. This worked in real Mathcad, but in Prime most things are mor cumbersome and time consuming (with the exception of editing matrices and using Ctrl-J in programs).
You must use the menu for results formatting

BTW, you are not solving equations but just evaluating mathematical expressions, terms ๐
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