Always attach the worksheet itself, not just a picture.
It looks like your equation has more than just one solution.
The solve block will give you the one based on your guess value.
The symbolic solve chose one of the solutions at its own will and it happens to be a different one.
You may try to put both solutions into your equation and see if they satisfy it (up to a certain inaccuracy)
Chances are that the solution of the symbolics will end up in an overflow (number exceeds 10^308)
You may try to add the modifier "assume, T2>100". It should help, but usually it doesn't and the symbolics will ignore it.
Guess you will have to stay with the numeric solve block.
BTW, using the numeric root() function in one of its two flavors instead of the solve block might be an option, too.