We have been taught that you must have the same number of equations as you have unknowns or a problem will not have a unique solution. Many problems ((your theta problem, for example) can be solve by simple algebraic manipulation. (You use one equation to eliminate a "variable" (Fn) from the second, leaving only one variable and constants.
We later learned that there was a matrix form of this that would solve it.
There are, however, forms of equations that resist/defy manipulation like that. For those situations we can use a solve block, and let Mathcad employ proven optimization techniques to find the solution. So you may use a solve block to solve all 2 variable/2 equation problems; but that does not mean it's always the "best" way.