The variable you want to solve for needs to be part of the equation. That is not the case above. You should have z_pna be a parameter to both SigmaT and SigmaC. This in turn means that also Tsr and Csrw must be functions, with z_pna as a parameter.
Considering that all other items are numerically defined, there's no need to try to solve this symbolically (which you do when you use that arrow). Better try a numerical solver, such as the root() function.
And when you really do want to use the symbolic solver:
1. You need to use the 'solve' keyword.
2. You should consider that the symbolic processor does not know about units by default, and while there is a setting to let it take account of them, sometimes it simply doesn't work.
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