Ah, you want the leader to come in at an angle to the chamfer surface instead of perpendicular? No, like a radial dimension, the leader line comes out perpendicular, and I believe this is required by standard.
However, you can show the dimension with the normal leader, then do Insert Note > With Leader, and make a note with a leader to the chamfer edge, at such angle as you like, with text "&d6" (where 6 is the dimension id, as seen in the dimension switched to symbolic when you are entering note text). You may not get all the dimension formatting possibilities there, because it's a note, but it'll do what you want.
If you can point out any standard that supports putting the leader line at an angle, we could look to implementing that as an enhancement, being a third possibility for the chamfer style.