Assuming you did all the standard configuration tasks...
- Created the org admin account at the organization level and populated the email address field.
- Assign org admin to the Organization > Administrators table (i.e. ORG_ADMIN group)
- Assigned org admin to the Organization> Creators table where relevant
Unless the org admin account has been explicitly added to the context team, org admin doesn't have browse rights to contexts created by site admin. The Products and Libraries tables show contexts that org admin is a member of.
This is a common issue with site administrators not being able to browse contexts created by org administrators. Org admin is still an administrator with full control permissions to contexts within their organization. As org admin, create a saved search for product and library contexts within their organization. Execute the search. From the search results, select the application context to access. Once accessed, org admin can access and browse them.
Not sure why the account can't save a copy of a profile.